Identify a metal by its density

Weigh an unknown metal painted grey, find its volume by water displacement, and compare the density — with its uncertainty — against handbook values to find out what it is.

Difficulty ●○○ ≈ 15 min

Aim Measure the density of an unknown metal sample and decide which metals agree with it within the measurement uncertainty.
Weighing · water displacement · propagated uncertainty

Density bench: identify the metal

Unknown sample #1
55.53gd = 0.01 g51015202525 mL51015202525 mLBeforeAfter

Every sample has been painted the same grey — density is your only clue.

10
20
Mass m
55.53 g
Volume ΔV = V₂ − V₁
—
Density ρ = m / ΔV
—
Uncertainty (2u)
—

Measured density against handbook values

Mg 1.74 g/cm³Al 2.70 g/cm³Ti 4.50 g/cm³Zn 7.13 g/cm³Sn 7.29 g/cm³Fe 7.87 g/cm³Ni 8.91 g/cm³Cu 8.93 g/cm³Ag 10.50 g/cm³Pb 11.34 g/cm³ MgAlTiZnSnFeNiCuAgPb024681012Density ρ / (g/cm³)

Read both levels and the density appears here.

Each sample’s true volume and mass are generated deterministically from its number, with mass = volume × the density in the element table (PubChem data, ~20 °C). The balance reads to 0.01 g; a cylinder reading is uncertain by a fifth of a division. The density uncertainty adds the relative uncertainties of m and ΔV in quadrature.

Procedure

  1. Pick an unknown sample. The balance (readability 0.01 g) shows its mass; record it.
  2. In the “before” lens, level your eye with the bottom of the meniscus and read the water volume V₁ to 0.1 mL.
  3. With the sample submerged, read V₂ the same way. The sample volume is ΔV = V₂ − V₁.
  4. Calculate ρ = m/ΔV and see which metals fall inside the ±2u band on the number line.
  5. Tick “Use half the sample”, repeat, and compare the two densities; finally reveal the sample and check your conclusion.

What to notice

  • Half a sample halves both mass and volume but not density — density is an intensive property.
  • The smaller the sample, the larger the relative uncertainty in ΔV and the wider the band — it may cover several metals at once.
  • Copper (8.93) and nickel (8.91), or zinc (7.13) and tin (7.29), are too close for displacement to separate; you need a second property such as colour or magnetism.
  • The volume readings, with only two or three significant figures, limit the density — not the balance.

In a real lab

  • Slide the sample down the tilted cylinder wall so no water splashes out and the base does not crack; check that no air bubbles cling to it.
  • The sample must be fully submerged and must not dissolve in or react with water; porous or coated samples give a low apparent density.
  • A narrower cylinder, a larger sample, or Archimedes’ method (weighing in air and in water) gives a better density.
  • Wash your hands after handling lead or other heavy-metal samples, and keep metal fragments out of the drain.

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