合成氨平衡:实测与计算

1923–1924 年在铁催化剂上测得的 3 : 1 氢氮混合气平衡氨含量,与本站由 NIST 热力学数据按理想气体算出的值并列。

35 行
3251010.3811.13−0.75
350107.357.89−0.54
375105.255.63−0.38
400103.854.06−0.21
425102.802.97−0.17
450102.042.20−0.16
475101.611.66−0.05
500101.201.27−0.07
3503017.8018.52−0.72
3753013.3514.02−0.67
4003010.0910.58−0.49
425307.598.01−0.42
450305.806.10−0.30
475304.534.68−0.15
500303.483.63−0.15
3505025.1125.68−0.57
3755019.4420.15−0.71
4005015.1115.68−0.57
4255011.7112.17−0.46
450509.179.45−0.28
500505.585.78−0.20
37510030.9530.520.43
40010024.9124.890.02
42510020.2320.130.10
45010016.3516.190.16
47510012.9812.99−0.01
50010010.4010.44−0.04
45030035.5031.983.52
47530031.0027.253.75
50030026.2023.093.11
45060053.6043.759.85
47560047.5038.708.80
50060042.1034.008.10
450100069.4052.3417.06
475100063.5047.4316.07

100 atm 以下两者相差不到 1 个百分点;更高压强下实测值更高,因为高压下的氨偏离理想气体(逸度系数小于 1)。

数据来源

  1. A. T. Larson, R. L. Dodge, “The ammonia equilibrium”, J. Am. Chem. Soc. 45, 2918–2930 (1923).
  2. A. T. Larson, “The ammonia equilibrium at high pressures”, J. Am. Chem. Soc. 46, 367–372 (1924).
  3. Computed values: NIST Chemistry WebBook Shomate parameters, ideal gases.

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