Henry’s-law constants of gases in water

Henry’s solubility constants at 25 °C and their temperature coefficients, with the 0 °C constants and air-saturated concentrations computed from them.

5 rows
Carbon dioxideCOX2\ce{CO2}0.03424000.0710.61
ArgonAr\ce{Ar}0.001413000.00210.51
OxygenOX2\ce{O2}0.001317000.00228.4
NitrogenNX2\ce{N2}6.1 × 10⁻⁴13009.1 × 10⁻⁴13
HeliumHe\ce{He}3.7 × 10⁻⁴2304.0 × 10⁻⁴7.5 × 10⁻⁶

The 0 °C values use kH(T) = kH(298 K)·exp[C(1/T − 1/298.15)], assuming a constant enthalpy of solution, and may be a few per cent low. Air-saturated values subtract the 25 °C water vapour pressure (3.17 kPa); CO₂ is taken as 420 ppm.

Sources

  1. R. Sander, “Compilation of Henry’s law constants (version 4.0) for water as solvent”, Atmos. Chem. Phys. 15, 4399–4981 (2015); rounded values as in its summary table.

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